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May 26th, 2013, 1:43am
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Calculation of pH Adjustment Dosing! (Read 191 times)
Nasir
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Calculation of pH Adjustment Dosing!
Feb 6th, 2008, 4:44am
 
Hello everybody;
Our RO produced water is showing a high pH value of more than 10. We only use Sodium Metabisolfate at feed inlet for chlorine neutralization, inlet water has pH of ~9.
1) What are the causes of this high pH?
2) Could anybody explain to me how to determine acid/ Alkali pH adjustment dosing rate and concentration?
Thank you for your help.
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DS
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Re: Calculation of pH Adjustment Dosing!
Reply #1 - Feb 7th, 2008, 10:16am
 
Dear Nasir,

I do not know why the pH goes up further till app. 10. The reaction of metabisulfite and Chlorine at this elevated pH is little documented, so the "cause" for pH going up further remains unknown to me. Or, maybe something else is going on?
I have however one remark: at pH of 9, the hypochlorite you dose has lost most of its disinfection power. The pH should be around 7.5 or less.
I can imagine that your RO installation is suffering from scaling at these elevated pH values.

In order to restore the pH of the RO-effluent at the desired value, you should do a lab test: make some titration curves with the acid you intend to use. Then make a mass balance (based on equivalents to dose) in order to choose the right pump rate range. Full scale: install a good pH sensor which automatically controls (PI-control) pump dosing rate of acid. Sensor is downstream dosing point and not too far away from it (minimise dead-time), but ensure excellent mixing before reaching the pH-sensor.
controlling pH at 7.00 is not that simple, so good parameterisation of controller is required.

best regards,

DS
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Ayrus
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Re: Calculation of pH Adjustment Dosing!
Reply #2 - Feb 7th, 2008, 1:22pm
 
Dear Nasir,

You must use acid dosing to reduce pH of feed water immediately or the caSo4 scaling will choke up the membrane irreversibly and will become difficult to treat. Yhis should have been suggested along with the system configuration. try to reduce ph of feed water to <6.

you should run the projections inorder to see the acceptability of the pH values. This is a must
Hope this will help you.
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With Best regards,
Ayrus
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