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Sep 8th, 2010, 5:29am
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Iron Oxidation Rates (Read 355 times)
Jimbob
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Iron Oxidation Rates
Jan 23rd, 2009, 2:15pm
 
Can anyone tell me what the typical oxidation rate of iron from ferrous to ferric is in the presence of sodium hypochlorite versus chlorine gas? I understand that oxidation with chlorine gas is typically 10 to 15 seconds, but I am having difficulty verifying the same or different rate for sodium hypochlorite solution (12.5%).

Thanks in advance.
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grrun
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Re: Iron Oxidation Rates
Reply #1 - Jan 24th, 2009, 12:12pm
 
I'm not sure that this may be of some help, but the oxidation of ferrous iron to ferric iron occurs rapidly with air at a pH of 8.5. Therefore, I suspect that pH may also be a significant variable for oxidation with hypochlours ion. If this type of oxidation is similiar, then sodium hypochlorite woud be my choice because of the excess NaOH in the sodium hypochlorite. However, the reaction may be so quick that the selection of reagent would depend on other considerations such as cost, availabilty, safety, etc.

grrun
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