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May 25th, 2013, 3:38pm
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plating wastewater treatment (Read 375 times)
nguyen kien
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plating wastewater treatment
Apr 20th, 2012, 1:32am
 
Hi all,
May be any one could tell me know, on the plating wastewater process, include hex chrome, cyanua, Ni; which one should be processed first and then?
I hope every one can show me
thank all
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nguyen kien
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Re: plating wastewater treatment
Reply #1 - Apr 20th, 2012, 5:03am
 
Realy nobody knew?
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Jeff Naumann
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Re: plating wastewater treatment
Reply #2 - Apr 20th, 2012, 7:37am
 
"Plating" is a very large number of individual processes.  Which specific plating are you asking about?  Is it "hexavalent chrome plating" of steel?  If that is the case, if memory serves me, the steel is cleaned, rinsed, plating with copper, rinsed, plated with nickle, rinsed, then plated with hex chrome, and finally rinsed.  I've probably left off a couple of steps.  But, using Google should produce the correct process.

Of course, there is also probably some means to chrome plate using trivalent chrome.  Then, there is a process for "black chrome" plating.
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Re: plating wastewater treatment
Reply #3 - Apr 20th, 2012, 12:49pm
 
Plating discharges are generally more economically treated at the source, before other waste streams are added. Treating the combined wastewater stream would involve a far more complicated process which would involve treating the entire wastewater stream. For example, cyanide would require pH elevation and oxidation (don't do this before chromium reduction because the low pH would liberate deadly hydrogen cyanide gas. Hexavalent chromium would require low pH reduction and elevated pH for precipitation of trivalent chromium for solids removal and nickel would probably require an elevated pH for solids removal.

A system using demineralized water could be utilized to reduce the loss of plating chemicals (cost saving) and reuse of wasted chemicals while reducing the potential discharge of prohibited substances. An engineering study of localized treatment versus centralized treatment should be presented to management.

grrun
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nguyen kien
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Re: plating wastewater treatment
Reply #4 - Apr 21st, 2012, 4:06am
 
I thank for your show very much
base on your show, in my way, i understood that the haex chrome would be processed to trivalent chrome first at low pH, and then  pH elevation io process cyanua to cyanate, last be precipitation at hight pH
many thanks.

nguyenkien
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Re: plating wastewater treatment
Reply #5 - Apr 21st, 2012, 10:42am
 
These processes and the treatment of waste stream have the potential to be quite dangerous if you don't really know what you are doing.  Here's some information:

http://www.nmfrc.org/bluebook/toc6.htm
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nguyen kien
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Re: plating wastewater treatment
Reply #6 - Apr 22nd, 2012, 3:56am
 
thank all again
your help realy be useful to me.
I think I will use it in my new treatment.
I also hope take your help for other
Best Regard
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Taoward Lee
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Re: plating wastewater treatment
Reply #7 - Apr 26th, 2012, 9:47am
 
The best pollution control for electroplating is PREVENTION by source reduction.

This means implementing:
1) Choosing low pollution chemistries
2) Low chemical concentrations of the process solutions
3) Multiple rinses to include static rinse to recover dragout especially for heated solution.

Waste minimization and pollution control for electroplating requires a lot of experience and knowledge to be done well. Find a good consultant.

Taoward Lee

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Re: plating wastewater treatment
Reply #8 - May 16th, 2012, 2:07am
 
In Hexavalent chromium plating chromium trioxide, as the main ingredient. It processed in following way.                                                        
1. activation bath                        
2. chromium bath                        
3. rinse                                  
4. rinse
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