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May 19th, 2013, 11:52am
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Removal of COD (Read 366 times)
Audioslave
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Removal of COD
Apr 28th, 2012, 12:07pm
 
Good Evening..!

I want to remove BOD & COD from rejected water of ROP # 1 Cause it is been used as feed for ROP # 2 but, if we look into the water analysis report  the COD is 98mg/l & BOD is 2.0mg/l.

So we required you involment in this project, some small modification can be done to remove COD from water.

Need your suggestions..! Attached water analysis report FYI

Hope to here you soon.! If you requires any details please let me know
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Jeff Naumann
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Re: Removal of COD
Reply #1 - Apr 28th, 2012, 12:35pm
 
I don't see an attachment.

Are "ROP#1" and "ROP#2" the two stages of a reverse osmosis system?
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Re: Removal of COD
Reply #2 - Apr 28th, 2012, 1:51pm
 
ROP # 1 is double pass RO Plant & the rejected water of it is being used as feed for ROP # 2.

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Re: Removal of COD
Reply #3 - Apr 28th, 2012, 1:59pm
 
If Jeff's comments are correct, you still need more information about the COD analysis. I would suggest that you first run a TOC analysis to determine if the COD is mostly long chain organics or an oxidizable inorganic substance (either may exhibit COD, but low BOD) and work from there to determine a possible treatment.

grrun
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Re: Removal of COD
Reply #4 - Apr 28th, 2012, 3:09pm
 
this is the full water analysis report of that rejected water of ROP # 1

1. floating particles                              nil
2. pH@ 25 C                                        6.7
3. TSS                                                 2.6mg/l
4. turbidity                                           1.5 NTU
5. BOD                                                 2 mg/l
6. COD                                                 98mg/l
7. temp                                                24.3 C
8. TOC                                                  1mg/l
9. total kjeldahl nitrogen (as N)               0.28mg/l
10. oil & gresase                                    NDLT 1mg/l
11. florecent petroleum matters               NDLT 0.05mg/l
12. phenols                                            NDLT 0.002mg/l
13. NH3-N                                              0.18mg/l
14. free residual chlorine                          NDLT 0.02mg/l
15. Total cyanide                                      NDLT 0.01mg/l


these are the details. nee you suggestions.
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Re: Removal of COD
Reply #5 - Apr 29th, 2012, 12:55pm
 
Now you need to look for oxidizable inorganics such as ferrous and other metallic compounds, sulfides, sulfites, etc.

I think that you need to know more about the source of water to ROP #1 to determine the source of the inorganic COD. This COD may not interfere with ROP #2 unless low solubility causes membrane plugging.

What are the processing problems that ROP #2 is experiencing?

grrun
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Re: Removal of COD
Reply #6 - Apr 29th, 2012, 2:54pm
 
the membranes for ROP 2 are getting choked with a period of min 2years..!
as compare to other it is perfectly workin for max 5 years..!
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Re: Removal of COD
Reply #7 - Apr 30th, 2012, 2:24pm
 
You need to explore the inorganics in the ROP#1 reject to determine which may be responsible for the membrane fouling. I would check AA or ICP tests for likely candidates and then see if they may form insoluble precipitates when oxidized. Another possibility is biological growth which can increase with time. There are "dip sticks" that can measure biological contamination in water.

Unless you have other data (such as the composition of the membrane fouling constituents), you are on your own to find the source of membrane fouling.

grrun
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Re: Removal of COD
Reply #8 - May 5th, 2012, 2:11am
 
HI all,

I am much concern about the COD present in water. It will effect the membrane in what basis? what is normal life of membrane if we are using raw water in which COD is 100mg/l.
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Re: Removal of COD
Reply #9 - May 5th, 2012, 4:15pm
 
COD is not a chemical compound! If the COD is responsible for membrane fouling; you'll have to determine which chemical or biological component that is a constituent of the COD that causes the fouling. My guess is that you need to focus on the fouled membranes to determine which constituent is causing the fouling. The identified constituent may be treated to eliminate it or you may have to live with shortened life if you cannot treat or remove it.

grrun
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