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May 24th, 2013, 12:07pm
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COD & TOC of industrail wastewater (Read 327 times)
Judy
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COD & TOC of industrail wastewater
May 25th, 2012, 9:38am
 
Dear all,

I would like to know that how I can get some info about COD of wsatewaters containing the following organics:
1- ethyl acetate 2- ethanol 3- acetic acid 4- acrylic acid 5- methyl acrylate 6- butyl acrylate 7-isopropanol 8- di ethylen glycol
9-tertiary butyl glycol

I want to know that how to get info about characteristics (COD & TOC) of  effluents containing the above-mentioned organics?
Thank you very much.
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Jeff Naumann
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Re: COD & TOC of industrail wastewater
Reply #1 - May 25th, 2012, 9:54am
 
That would very much depend upon the concentration of the chemical in the waste water.  Why not make up a sample of what you want to know about, and have it tested for COD and TOC?
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Tom Keenan - nesa
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Re: COD & TOC of industrail wastewater
Reply #2 - May 25th, 2012, 9:54am
 
No doubt the theoretical values can be worked out from first principles, or you could check the MSDS sheets for each chemical and use that information to make a reasonable estimate, but the most appropriate way to do this is to test the wastewater stream.
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Judy
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Re: COD & TOC of industrail wastewater
Reply #3 - May 25th, 2012, 10:42am
 
Thank you very much but is there any way to get this information from the companies producing these organics? for example companies in the US or Europe that produce these materials may give the information about the characteristics of the wastewater of the plants?
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Jeff Naumann
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Re: COD & TOC of industrail wastewater
Reply #4 - May 25th, 2012, 11:24am
 
Maybe.  Why don't you contact them?
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Judy
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Re: COD & TOC of industrail wastewater
Reply #5 - May 25th, 2012, 1:47pm
 
because I do not have their website or email address. I could not find the website of the companies through google searching. I do not know how to find them.
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DrHenry
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Re: COD & TOC of industrail wastewater
Reply #6 - May 25th, 2012, 2:24pm
 
You are not going to find the specific data you seek since no facility will only manufacture one of those chemicals or a combination of just those chemicals.  The data will also vary greatly from near zero to hundreds of mg/L.  There will be no specific values.  You may find some data on facilities looking at USEPA TRI data.  I don't think it would help since those facilities will not talk to you and getting copies of their permit reports is not straightforward.  My only suggestions are to call industry groups.  Start here:

http://www.epa.gov/oecaerth/resources/publications/assistance/sectors/notebooks/organic.pdf

You can also look on Envirofacts, but you need some data.  You could try facility names such as Dupont, Dow, etc.

http://www.epa.gov/enviro/

A recommendation is to search Google Scholar and Scirus for research articles.

http://scirus.com/

http://scholar.google.com/schhp?sourceid=navclient&ie=UTF-8
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Re: COD & TOC of industrail wastewater
Reply #7 - May 25th, 2012, 3:40pm
 
You can determine the TOC value of each of those compounds pretty easily. I'll start you off with the first one

Ethyl Acetate (C4H8O2) MW = 88 There are 4 carbons comprising 54.5% of the total molecular weight. So for every 100 mg/L ethyl acetate you will have 54.5 mg/L TOC.

The COD calculation is a little trickier because you have to get the oxidation equation all balanced.

Again, for Ethyl Acetate I'll start you off
C4H8O2 + 5O2 -> 4 CO2 + 4 H2O (Note if you have nitrogen in your compound be sure to oxidize to ammonia)

The calculation is (Concentration/MW) * (moles O2/moles compound) * 32

For 100 mg/L ethyl acetate you get (100/88)*(5/1)*32= 181.8 mg/L COD.
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