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May 21st, 2013, 11:01pm
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TDS to Conductivity ratio? (Read 291 times)
Andres
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TDS to Conductivity ratio?
May 29th, 2012, 6:54am
 
Hello,

I have another of those newbe questions, but eveyone has been so helpful to me answering all my previous ones.

I got results from the lab, that the
TDS = 3050 mg/L
Conductivity = 30 000 microS/cm

How likely is this? One of my collegues told me that he read the Conductivity to TDS ratio is usually in the range of 1,3 - 2.

If it is water dependant, then I am talking about a phenolic water stream comming from retorting - had a few questions earlier about that here on the forums.

Best regards, and thank you in advance,
Andres
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David S.
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Re: TDS to Conductivity ratio?
Reply #1 - May 29th, 2012, 8:34am
 
My best guess is that your TDS numbers are biased low. Phenol is a somewhat volatile compound and boils around 180 C. This happens to be the temperature used for TDS determination.
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Re: TDS to Conductivity ratio?
Reply #2 - May 29th, 2012, 10:43am
 
Don't forget that pH and temperature can affect conductivity. The relationship between conductivity and TDS will vary with the nature of the TDSs.

grrun
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Re: TDS to Conductivity ratio?
Reply #3 - May 29th, 2012, 3:24pm
 
There's no hard and fast relationship between TDS and Sp. cond. It depends on the ions present.

It might be instructive to dilute the sample at 4 - 5 different levels and observe the relationship of Sp. cond. to dilution level.

Apart from that, I agree with the other posters. Phenol will fly right up the chimmney at 180 C. However, it's not a very strong electrolyte, either.
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Andres
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Re: TDS to Conductivity ratio?
Reply #4 - May 31st, 2012, 1:23am
 
Thank you all for your most helpful answers
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