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May 25th, 2013, 3:38pm
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Reducing Phophorous Levels (Read 116 times)
Stacy OBryan
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Reducing Phophorous Levels
Jun 05th, 2012, 1:55pm
 
I have a package treatment plant that treats approximately 10,000 gallons a day. Our permit requires our daily average of phosphorus to be under 1 mg/L. We are having trouble getting these levels. For instance last month we had the following: .45 mg/L, .72 mg/L, 1.49 mg/L, .37 mg/L and 2.30. How can it be so low one week and then high the next? Is there a simple solution to get these levels down?
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Cara
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Re: Reducing Phophorous Levels
Reply #1 - Jun 5th, 2012, 6:46pm
 
I'm not sure the details of your treatment process, but we used to have wildly different phosphorus levels from week to week, even day to day. We have a biological treatment plant to treat our industrial waste (chemical plant).

With the treatment process, phosphorus levels heavily depends on what is being sent with the influent waste stream and (in the case of biological treatment), the population and health of the microorganisms. I found the best way to keep the levels in check was to monitor them every other day through the use of Chemetrics tests (not good for reporting levels to regulatory agencies, but good enough to make sure the levels are monitored closely and adjusted accordingly).  

If you do biological treatment, let me know and I can offer more advice. If not though, I wish you luck!
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Re: Reducing Phophorous Levels
Reply #2 - Jun 5th, 2012, 9:59pm
 
Try running unfiltered and filtered samples for phosphorus. If your TSSs vary, the P in the activated sludge organisms may cause this variability in P results.

grrun
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Re: Reducing Phophorous Levels
Reply #3 - Jun 6th, 2012, 1:04am
 
'How can it be so low one week and then high the next?'

There is no large variability in your values. I would say they are usually low.

Suspended solids was a good hint.
What is the precision of the analytical determination?
Having an equalization tank should further make the effluent quality even more stable.

Kind regards
T. Sobisch
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Re: Reducing Phophorous Levels
Reply #4 - Jun 6th, 2012, 10:59am
 
if the P is due to TSS this needs to be addressed (either optimizing the biology or perhaps a settling aid), if soluble I suggest increasing the chemical feed rate (ferric, alum etc), be sure to check the alkalinity when you do this. To optimize your rate you can test the orthophoshate in the filtered MLSS at the end of your process and get an idea what dose you need to minimize chemical costs and extra sludge production from them. Some plants will just overdose a little bit- this won't hurt except a little in the pocketbook provided the pH doesn't drop on you.

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