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Jun 18th, 2013, 1:59am
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very saline (170 g/l CacL2) feed (Read 265 times)
Alin
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very saline (170 g/l CacL2) feed
Jun 18th, 2012, 11:15am
 
what would be the methods to treat this very saline feed? The one pass efficiency would not be a factor and the quality of the product does not exceed the process water quality.
Thank you
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grrun
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Re: very saline (170 g/l CacL2) feed
Reply #1 - Jun 18th, 2012, 10:39pm
 
What quantity or flow? What other contaminants are in the solution? What are the discharge limits?

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Alin
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Re: very saline (170 g/l CacL2) feed
Reply #2 - Jun 19th, 2012, 8:49am
 
the flow is about 2,000 m3/day and the quality of discharge goes a bit under the effluenht dicharge (for North Ameerica) as they want to recyccle all of it as process water
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Alin
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Re: very saline (170 g/l CacL2) feed
Reply #3 - Jun 19th, 2012, 8:51am
 
The major contaminant is CaCl2 other than that only trace elements (P, F, N)
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Re: very saline (170 g/l CacL2) feed
Reply #4 - Jun 19th, 2012, 2:35pm
 
Even if you could remove most of the calcium (possibly by adding sodium carbonate), you would still have the chlorides which would be pretty corrosive for process water. I don't think that ion exchange would be practical or economical.

What kind of process would recycle this concentrated corrosive brine as process water?

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Alin
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Re: very saline (170 g/l CacL2) feed
Reply #5 - Jun 19th, 2012, 2:46pm
 
The brine could not be recycled as it is due to high chlorides and calcium. There are few options to reduce their content (probably something as two processes in series, like high ph lime followed by RO). The main target is not the recovering of water but reducing the volume of final waste.
The crystallization of CaCl2 is not really an option as the solids would have to go through a gel phase that can cause big operational problems
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