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May 25th, 2013, 12:47pm
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chlorine dioxide and TRC in effluent (Read 208 times)
SoGaSR75
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chlorine dioxide and TRC in effluent
Aug 05th, 2012, 6:05pm
 
Due to some TRC effluent limits a dechlorinator using sodium bisulfite was added.  Original estimate for dosing was 1.5 gallons/day.  Flow out effluent (direct discharge) is about .2 to .3 MGD.  The levels have been running about .1 mg/l and reduced to .01-.03mg/l.

Operator has bumped up to 5 gallons per day despite my advice because he wants 0.0mg/l.  Can anyone provide guidance on why he would need to bump it up that much?  Does he have risk of exceeding the BOD limit?  Injection point is just prior to GAC filters if that matters.

Based on what I have researched I would agree that 1.5-2 gal/day should be adequate.

Appreciate any guidance.
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SoGaSR75
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Re: chlorine dioxide and TRC in effluent
Reply #1 - Aug 5th, 2012, 6:06pm
 
Great site by the way!  And thanks in advance!
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Re: chlorine dioxide and TRC in effluent
Reply #2 - Aug 5th, 2012, 9:06pm
 
I think that TRC is determined by grab samples unless you are permitted for continuous monitoring. If you are running TRC on grab samples, then flow and concentration variability may become an issue. Now, the maximum concentration limit was for direct discharge (if I remember rightly) is 0.05 mg/L and the GAC may even reduce the concentration lower.

Bisulfite is also an oxygen scavenger so that an excess may have an impact on BOD results and chemists are permitted to react the BOD samples with something (I forget what) to react with the sulfite before setting up the BOD samples.

Now if it is the cost that you are worried about; you and the operator are less concerned about the cost than about the effect on discharge limits. Why don't you suggest that the operator not change the pumping rate and start a statistical process control chart for both BOD and TRC. This would be a better solution tha arguing over calculations that may not considered all the significant variables. Then you may or may not be able to justify a change in feed rates.

grrun
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SoGaSR75
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Re: chlorine dioxide and TRC in effluent
Reply #3 - Aug 6th, 2012, 4:40am
 
You are correct .05 & grab samples

Thanks, essentially I told him we need to keep track of the values not only from the outfall but pumprate, influent trc, and we might add another parameter to it now.  The outfall numbers were less than the limit and he continued to increase the pump rate each day because he wanted 0.0.  Each day the pump would get moved up and he wasn't even aware of how much TRC was in the stream prior to dechlorination.  Of course $$$ went through my mind since we would 2x or 3x the estimate we expected, but I was also wanted to make sure we don't get tunnel visioned and blow another parameter in the quest for 0.0 when in my opinion that is not necessary Smiley

Would the bisulfite react with chlorine attached to the GAC?
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