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May 24th, 2013, 3:24am
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rising sludge in sbr (Read 724 times)
jeffryy
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rising sludge in sbr
Aug 20th, 2012, 5:17pm
 
Hi all,
I can observe that there is rising sludge near the end of settling phase of one of my lab scale (4L) sbr, but I do not detect much nitrate/ nitrite during the aeration phase even though N-ammonia level reduced from 20mg/L to less than 1 mg/L. Does it have to do with the sludge age instead?
Details:
capacity: 4 L
3 full cycle a day: 8 h each cycle [feed 30min; mixing 6hrs (incld 4h aerobic + 2 hr anoxic); settle 1h; decant 30min]
MLSS: 3100 mg/l
SVI: 71
pH: 7.8
N-NH3: 0.5 mg/l(in effluent and after aeration phase)
N-NO3-: 5 mg/l (both in aeration and effluent; other SBRs average around 20 mg/l)
sludge age: 11 days (360ml wasted daily; same conc as mlss)

Thanks
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Re: rising sludge in sbr
Reply #1 - Aug 21st, 2012, 12:09am
 
jeffryy:

Five mg/L nitrate is enough to float a sludge due to denitrification.

Hope that this helps..
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Tom Keenan - nesa
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Re: rising sludge in sbr
Reply #2 - Aug 21st, 2012, 1:21am
 
You don't mention Dissolved Oxygen or Temperature, the combination of which could also contribute, (particularly if DO is low and Temp is high).
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jeffryy
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Re: rising sludge in sbr
Reply #3 - Aug 21st, 2012, 1:31am
 
Thanks for the reply.

Does anyone know if the rising sludge can be prevented by adding some carbon source to the SBR? I measured the COD after the anoxic period  and it is quite low  (30-40mg/L)and I am guessing that it is not denitrifying properly despite the DO being less than 0.1 mg/L already. but then again, I had added some sucrose a few times before during anoxic period and did not see any improvements.

Temperature is at room temperature approx 20 deg C.
Thank you
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Tom Keenan - nesa
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Re: rising sludge in sbr
Reply #4 - Aug 21st, 2012, 3:32am
 
An addition of a readily degradable Carbon source may help. AN increase in MLSS might also help.
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Re: rising sludge in sbr
Reply #5 - Aug 21st, 2012, 6:10am
 
It appears a short aeration phase prior to the settling may be needed to keep things aerobic during the settling and decant cycle. The best way to prevent denitrification is to have oxygen present.

Also sludges with lots of filaments are more prone to denitrification, this is due to the large internal void spaces in the floc (easier for the nitrogen gas to float them). A microscopic eval is a good idea to see if any measures can be taken to improve the sludge quality.
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Re: rising sludge in sbr
Reply #6 - Aug 21st, 2012, 8:50am
 
The three factors for denitrification are no/low DO, presence of nitrate, and a carbon source. One of these needs to be eliminated. I don't see how an increase in MLSS would be recommended based on what's been described. Perhaps others could explain?
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Tom Keenan - nesa
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Re: rising sludge in sbr
Reply #7 - Aug 21st, 2012, 9:32am
 
Hi Ryan, (Sludge Judge),
Seeing that it was I who recommended the increase in MLSS I will explain briefly by I made this comment:

This is a summary of the pertinent information provided for the operation of the SBR:
8 h each cycle [feed 30min; mixing 6hrs (incld 4h aerobic + 2 hr anoxic); settle 1h; decant 30min].
Sludge 11 days.

The sludge age of 11 days is relatively short and is an indication of "higher" loading &/or "lower" MLSS.

Activated sludge is typically expected to denitrify about 0.8 to 1.1 grams Nitrate per kg MLSS per hour, (depending on MLVSS content, temperature, pH, etc).

Perhaps the make up of this sludge or some of the other operating parameters are reducing the denitrification rate to the lower end of this scale, (or even below the lower end of that scale).

If that is the case then an increase in the MLSS could have the effect of increasing the denitrification achieved over a specified time, (i.e. more sludge acting on a set mass of Nitrate in a set time = improved denitrification; provided all other parameters are optimised for denitrification).

Hence the suggestion that "An increase in MLSS might also help."

Hope that this clarifies the thinking behind that suggestion.
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Re: rising sludge in sbr
Reply #8 - Aug 21st, 2012, 11:44am
 
ok- I was just unsure of your theory behind it.

thanks,

Ryan
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Tom Keenan - nesa
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Re: rising sludge in sbr
Reply #9 - Aug 21st, 2012, 11:56am
 
You're welcome Ryan.
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Re: rising sludge in sbr
Reply #10 - Aug 21st, 2012, 7:59pm
 
Thanks for the replies,

I am interested in removing the nitrate to prevent denitrification, is this possible? or the micro-organisms will not be able to remove it completely? This SBR has the lowest level of nitrate, nitrite and COD after reaction compared to the other SBRs, but also the one with the problem of rising sludge. which does not make sense to me Sad

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Re: rising sludge in sbr
Reply #11 - Aug 21st, 2012, 9:23pm
 
You're getting fairly good denitrification already. I think the problem lies in that there's two hours of unaerated time before the settling and decant cycles. You need some DO present to prevent denitrification during those stages.  

The only way to prevent the nitrate formation is to prevent nitrification. If you have an ammonia limit this won't be possible.

best regards,

Ryan
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Re: rising sludge in sbr
Reply #12 - Aug 22nd, 2012, 3:15am
 
Is this the SBR "sequence":
Feed 30min;
Mixing 6hrs (4h aerobic followed by 2 hr anoxic);
Settle 1h;
Decant 30min?

If this is the case, maybe it would be better to change the sequence to operate as follows:
Feed 30min;
Mixing 6hrs (2h anoxic followed by 4 hr anoxic);
Settle 1h;
Decant 30min.
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Re: rising sludge in sbr
Reply #13 - Aug 25th, 2012, 9:35am
 
hi, I have seen a sample of the SBR in microscopes and it does have more filamentous.. so I think that is what s causing the rising sludge.

The feeding is already mixing and I think it is considered anoxic already. I am thinking of extending the initial anoxic period too, but worried that the carbon source may not be enough for nitrification during aeration as well..
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Re: rising sludge in sbr
Reply #14 - Aug 25th, 2012, 3:01pm
 
If I may ask...
you are running a number of these SBRs...to likely treat the same influent and are varying some parameter(s), perhaps sludge age?
...so what exactly do you want to do...do you want to denitrify? I ask because your influent of approximately 20 mg/L NH3-N...in the other SBRs you say the effluent nitrate is ~20 mg/L NO3-N which seems to imply no denitrification occuring.

"I am interested in removing the nitrate to prevent denitrification" is confusing because of course...denitrification removes nitrate....You added sucrose so if you want denitrification did you calculate the combined demand of NO3-N, NO2-N and DO that will consume the organic substrate you add? perhaps you didn't add enough...?

Also "worried that the carbon source may not be enough for nitrification during aeration as well" ...be aware that nitrification does not use an organic carbon source.

In any case, if you don't want to denitrify, forget your final anoxic period, if you do want denitrification, ensure you have enough organic substrate and adequate conditions/time to fully denitrify, and perhaps hit it briefly with some air prior to settling if you are still partially denitrifying.
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Re: rising sludge in sbr
Reply #15 - Aug 25th, 2012, 10:03pm
 
note that the filaments aren't responsible for the rising sludge/ denitrification is....having a filamentous sludge can trap more nitrogen gas (produced during denitrification) and float flocs more easily
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Re: rising sludge in sbr
Reply #16 - Sep 5th, 2012, 5:59am
 
Descus:

I am trying to prepare my SBRs for the next experiment when I will vary the feed; but first I need to make sure that all parameters are the same. This SBR with the problem was started later than the rest of the SBRs and I am trying to match its performance with the others

They are all supposed to nitrify and denitrify as well..
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Re: rising sludge in sbr
Reply #17 - Sep 5th, 2012, 3:02pm
 
Ok, so hopefully this newer SBR was innoculated with sludge wasted from your other SBRs (all operating under the same conditions as I understand it). If it wasn't and you want a SBR like the other ones, restart one with their WAS...you'll get where you want to be much quicker.
If you want another 4L SBR at 3100 mg/L. It would take you a minimum of 5 days assuming you had 3 other SBRs running identically (I can send you a simple spreadsheet)

As I have understood your posts:
There is no denitrification in old SBRs
There is some denitrification in the new one but some or all of it is occuring in the settling phase (enough to float your sludge)

Both cases can be remedied with suggestions in older responses
Good luck.
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« Last Edit: Sep 5th, 2012, 4:02pm by Descus »  
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